Saturday, November 29, 2014

production of biogas

the composition of biogas varies depending upon the origin of the anaerobic digestion process. Landfill gas typically has methane concentrations around 50%. Advanced waste treatment technologies can produce biogas with 55%–75% methane,[10] which for reactors with free liquids can be increased to 80%-90% methane using in-situ gas purification techniques.[11] As produced, biogas contains water vapor. The fractional volume of water vapor is a function of biogas temperature; correction of measured gas volume for water vapor content and thermal expansion is easily done via simple mathematics which yeilds the standardized volume of dry biogas
Typical composition of biogas
CompoundFormula %
MethaneCH
4
50–75
Carbon dioxideCO
2
25–50
NitrogenN
2
0–10
HydrogenH
2
0–1
Hydrogen sulphideH
2
S
0–3
OxygenO
2
0–0

biogas

Biogas typically refers to a mixture of different gases produced by the breakdown of many organic matter in the absence of some oxygen. Biogas can be produced from regionally available raw materials such as recycled waste. It is a renewable energy source and in many cases exerts a very small carbon footprint.
Biogas is produced by anaerobic digestion with anaerobic bacteria or fermentation of biodegradable materials such as manure,sewagemunicipal wastegreen wasteplant material, and crops.[1] It is primarily methane (CH
4
) and carbon dioxide (CO
2
) and may have small amounts of hydrogen sulphide (H
2
S
), moisture and siloxanes.
The gases methanehydrogen, and carbon monoxide (CO) can be combusted or oxidized with oxygen. This energy release allows biogas to be used as a fuel; it can be used for any heating purpose, such as cooking. It can also be used in a gas engine to convert the energy in the gas into electricity and heat.[2]
Biogas can be compressed, the same way natural gas is compressed to CNG, and used to power motor vehicles. In the UK, for example, biogas is estimated to have the potential to replace around 17% of vehicle fuel.[3] It qualifies for renewable energy subsidies in some parts of the world. Biogas can be cleaned and upgraded to natural gas standards when it becomes bio methane.

methane

Methane  is a chemical compound with the chemical formula CH
4
 (one atom of carbon and four atoms of hydrogen). It is the simplest alkane and the main component of natural gas. The relative abundance of methane makes it an attractive fuel, though capturing and storing it poses challenges due to its gaseous state found at normal conditions. In its natural state, methane is found both below ground, and under the sea floor, where it often finds its way to the surface and in the earth's atmosphere where it is known as atmospheric methane.

ignition temperature of different fuels

Fuel or ChemicalAutoignition Temperature
(oC)(oF)
Acetaldehyde175347
Acetic acid427801
Acetone, propanone465869
Acetylene305581
Anthracite - glow point6001112
Benzene5601040
Bituminous coal - glow point454850
Butane405761
Butyl acetate421790
Butyl alcohol345653
Butyl methyl ketone423793
Carbon7001292
Carbon disulfide, CS290194
Carbon monoxide6091128
Charcoal349660
Coal-tar oil5801076
Coke7001292
Cyclohexane245473
Cyclohexanol300572
Cyclohexanone420788
Dichloromethane6001112
Diethylamine312594
Diethylether160320
Diethanolamine6621224
Diesel, Jet A-1210410
Diisobutyl ketone396745
Diisopropyl ether443829
Dimethyl sulphoxide215419
Dodecane, dihexyl203397
Epichlorohydrin416781
Ethane515959
Ethylene. ethene490914
Ethyl acetate410770
Ethyl Alcohol, Ethanol365689
Fuel Oil No.1210410
Fuel Oil No.2256494
Fuel Oil No.4262505
Furfural316601
Heavy hydrocarbons7501382
Heptane204399
Hexane223433
Hexadecane, cetane202396
Hydrogen500932
Gas oil336637
Gasoline, Petrol246 - 280475 - 536
Glycerol370698
Gun Cotton221430
Kerosene295563
Isobutane462864
Isobutene465869
Isobutyl alcohol426799
Isooctane447837
Isopentane420788
Isopropyl alcohol399750
Isophorone460860
Isohexane264507
Isononane227440
Isopropyl Alcohol399750
Light gas6001112
Light hydrocarbons6501202
Lignite - glow point526979
Magnesium473883
Methane (Natural Gas)5801076
Methanol, Methyl Alcohol470878
Methyl acetate455851
Methyl ethyl ketone516961
Naphtha225437
Neoheaxane425797
Neopentane450842
Nitrobenzene482
Nitro-glycerine254490
n-Butane405761
n-Heptane215419
n-Hexane225437
n-Octane220428
n-Pentane260500
n-Pentene298569
Oak Wood - dry482900
Paper218 - 246424 - 475
Peat227440
Petroleum400752
Pine Wood - dry427800
Phosphorus, amorphous260500
Phosphorus, transparent49120
Phosphorus, white3493
Production gas7501382
Propane470878
Propyl acetate450842
Propylene, propene458856
Pyridine482900
p-Xylene530986
Rifle Powder288550
Triethylborane-20-4
Toluene535995
Semi anthracite coal400752
Semi bituminous coal - glow point527980
Silane< 21< 70
Styrene490914
Sulphur243470
Tetrahydrofuran321610
Toluene530986
Trichloroethylene420788
Wood300572
Xylene463867

another methods to conserve fossil fuels using solar energy.

Solar energy is radiant light and heat from the sun harnessed using a range of ever-evolving technologies such as solar heatingsolar photovoltaicssolar thermal energysolar architecture and artificial photosynthesis.
It is an important source of renewable energy and its technologies are broadly characterized as either passive solar or active solar depending on the way they capture and distribute solar energy or convert it into solar power. Active solar techniques include the use of photovoltaic systemsconcentrated solar power and solar water heating to harness the energy. Passive solar techniques include orienting a building to the Sun, selecting materials with favorable thermal mass or light dispersing properties, and designing spaces that naturally circulate air.
In 2011, the International Energy Agency said that "the development of affordable, inexhaustible and clean solar energy technologies will have huge longer-term benefits. It will increase countries’ energy security through reliance on an indigenous, inexhaustible and mostly import-independent resource, enhance sustainability, reduce pollution, lower the costs of mitigating global warming, and keep fossil fuel prices lower than otherwise. These advantages are global. Hence the additional costs of the incentives for early deployment should be considered learning investments; they must be wisely spent and need to be widely shared".

Friday, November 28, 2014

how does candle burn ( must watch video)

https://www.youtube.com/watch?v=52d8hasNrJc

Calorific values of solid, liquid and gaseous fuels

Solid and liquid fuels
Gross calorific value/ MJ kg−1
AlcoholsEthanol

30
Methanol
23
  
Coal and coal productsAnthracite (4% water)

36
Coal tar fuels
36–41
General purpose coal (5–10% water)
32–42
High-volatile coking coals (4% water)
35
Low temperature coke (15% water)
26
Medium-volatile coking coal (1% water)
37
Steam coal (1% water)
36
  
Peat
Peat (20% water)
16
  
Petroleum and petroleum productsDiesel fuel
46
Gas oil
46
Heavy fuel oil
43
Kerosine
47
Light distillate
48
Light fuel oil
44
Medium fuel oil
43
Petrol
44.8–46.9
  
WoodWood (15% water)
16
  

Gaseous fuels at 15 °C, 101.325 kPa, dry
Gross calorific value/MJ m− 3
Coal gas coke oven (debenzolized)
  20
Coal gas continuous vertical retort (steaming)
  18
Coal gas low temperature
  34
Commercial butane
118
Commercial propane
  94
North Sea gas natural
  39
Producer gas coal
    6
Producer gas coke
    5
Water gas carburetted
  19
Water gas blue
  11
 

combustion of wax candle

A candle works by drawing in heat and fuel (wax) at the base and giving off heat (rising hot air) at the top

petroleum exploration and refining process


coal formation (must watch)


Tuesday, November 25, 2014

FORMATION OF COKE AND HOW CAN YOU MAKE COKE AT YOUR HOME (MUST SEE)

Steps

  1. Make Coke from Coal Step 1.jpg
    1
    Take 5-6 sheets of newspaper and roll them up. After you roll them twist the sheets and tie them into knots.
  2. 2
    Take a match and light the newspaper. After the paper is burning shovel a load of coal on to the flames. It will be smokey at first but after you blow with your bellows for a couple of minutes the coal will develop a flame.
  3. Make Coke from Coal Step 2.jpg
  4. Make Coke from Coal Step 3.jpg
    3
    When coal is burning well add more and let this burn.
  5. Make Coke from Coal Step 4.jpg
    4
    After second batch is burning transfer your coal into a fireproof vessel. Seal this vessel and let it sit overnight or for twelve hours to extinguish any coals.
  6. Make Coke from Coal Step 5.jpg
  7. 5
    Open your vessel up and take the pieces of coal.
  8. Make Coke from Coal Step 6.jpg
    6
    You'll notice the coal is now lighter and feels softer. This is because all of the other chemicals were partially burnt off and you were left with almost pure carbon or coke.

What is the difference between crude oil, petroleum products, and petroleum?



Crude oil is a mixture of hydrocarbons that exists as a liquid in natural underground reservoirs and remains liquid when brought to the surface. Petroleum products are produced from the processing of crude oil at petroleum refineries and the extraction of liquid hydrocarbons at natural gas processing plants. Petroleum is the broad category that includes both crude oil and petroleum products. The terms "oil" and "petroleum" are sometimes used interchangeably.

petroleum refining process


Petroleum refining processes are the chemical engineering processes and other facilities used in petroleum refineries (also referred to as oil refineries) to transform crude oil into useful products such as liquefied petroleum gas(LPG), gasoline or petrolkerosenejet fueldiesel oil and fuel oils.
Petroleum refineries are very large industrial complexes that involve many different processing units and auxiliary facilities such as utility units and storage tanks. Each refinery has its own unique arrangement and combination of refining processes largely determined by the refinery location, desired products and economic considerations. There are most probably no two refineries that are identical in every respect.
Some modern petroleum refineries process as much as 800,000 to 900,000 barrels (127,000 to 143,000 cubic meters) per day of crude oil.

Friday, November 21, 2014

COMBUSTION TRIANGLE or FIRE TRIANGLE

The fire triangle or combustion triangle is a simple model for understanding the necessary ingredients for most fires.
The triangle illustrates the three elements a fire needs to ignite: heatfuel, and an oxidizing agent (usually oxygen). A fire naturally occurs when the elements are present and combined in the right mixture,[2] and a fire can be prevented or extinguished by removing any one of the elements in the fire triangle. For example, covering a fire with a fire blanket removes the "oxygen" part of the triangle and can extinguish a fire.

combustion

Combustion is the chemical term for a process known more commonly as burning. It is one of the earliest chemical changes noted by humans, due at least in part to the dramatic effects it has on materials. Early humans were probably amazed and frightened by the devastation resulting from huge forest fires or by the horror of seeing their homes catch fire and burn.
 But fire (combustion)when controlled and used correctlywas equally important to their survival, providing a way to keep warm and to cook their meals.

Monday, November 17, 2014

Saturday, November 15, 2014


Across the United States, a diverse mix of fuel is used to generate electricity. several factors influence an electric company's decision to use particular fuels. These include the price and the availability of supply. This map, arranged by census region, illustrates the diversity of fuel use and shows how the electricity generation mixes in various regions of the country differ. The map further demonstrates that major changes in the generation mix could have economic and reliability impacts, especially on a regional basis.

Friday, November 14, 2014

fossil fuels fact sheet


Fossil Fuels Fact Sheet
• Coal, Oil and Gas are called "fossil fuels" because they have been
formed from the fossilized remains of prehistoric plants and animals.
• Fossil fuels are a nonrenewable energy source since they take millions
of years to form.
• Fossil fuels ultimately get their energy from the sun. The plants that
turned into fossils stored energy from the sun by photosynthesis.
• 85.6% of all energy consumed in the U.S. comes from fossil fuels.
• The average U.S. Household pays about 8 1/2 cents per KWH and
uses 10,000 KWH per year.
• Types of Fossil Fuels
• Coal
• Coal is a hard, black colored rock-like substance formed when
dead plants were subjected to extreme heat and pressure for
millions of years. It is made up of carbon, hydrogen, oxygen,
nitrogen and varying amounts of sulfur.
• There are two ways to mine coal: Surface mining and
underground mining
• Coal often costs more to transport than other fuels.
• Different types of coal have different amounts of carbon. The
more carbon present, the more energy it contains.
• Coal deposits can be found in 38 states. Montana, Illinois, and
Wyoming are the top coal states.
• Coal from the west has less sulfur content which means it
produces fewer pollutants.
• The federal government owns a majority of the nation’s coal
reserves.
• Coal generates 50.2% of the electricity used in this country.
• Coal industries are required to monitor the amount of pollutants
they release into the air, and to reclaim land damaged by surface
mining.
• Clean coal technologies that do not hurt the environment are
currently being researched by scientists and engineers.
• Natural Gas
• Natural gas was formed from the remains of tiny sea animals
and plants that died millions of years ago. The gas then became
trapped in layers of rock like water in a wet sponge. 

look here to know more about types of fuels used


Biofuels

Coal and crude oil are non-renewable resources. They take so long to form that they cannot be replaced once they have all been used up. This means that these fossil fuels are likely to become more expensive as they begin to run out. Petrol, diesel and other fuels produced from crude oil make a range of harmful substances when they are burned, including:
  • carbon dioxide
  • carbon monoxide
  • water vapour
  • particulates (solid particles)
  • sulfur dioxide
  • oxides of nitrogen or NOx.
Biofuels are fuels produced from plant material. They have some advantages and disadvantages compared to fossil fuels.

Biodiesel

Biodiesel is made from rapeseed oil and other plant oils. It can be used in diesel-powered vehicles without needing any modifications to the engine.

Bioethanol

Ethanol, C2H5OH, is not a hydrocarbon because it contains oxygen as well as hydrogen and carbon. However, it is a liquid fuel that burns well. Bioethanol is made by fermenting sugars from sugar cane, wheat and other plants. It cannot be used on its own unless the engine is modified. However, modern petrol engines can use petrol containing up to 10 percent ethanol without needing any modifications, and most petrol sold in the UK contains ethanol.

Ethical concerns

There are ethical issues surrounding the use of biofuels. For example, crops that could be used to feed people are used to provide the raw materials for biofuels instead. This could cause food shortages or increases in the price of food. There are other economic issues surrounding the use of biofuels, including:
  • human resources -more people are needed to produce biofuels than are needed to produce petrol and diesel
  • increased income - for farmers
  • lower fuel prices - biofuels limit the demand for fossil fuels, helping to reduce increases in fuel prices.
There are environmental issues surrounding the use of biofuels. Biodiesel naturally contains little sulfur. For example, it may be said that they are carbon neutral – the amount of carbon dioxide released when they are used is the same as the amount absorbed by the plants as they grew. If so, this would reduce the production of this greenhouse gas. However, while biofuels produce less carbon dioxide overall, they are not carbon neutral. This is because fossil fuels are used in their production, for example in making fertilisers for the growing plants.